Solid metal will not ignite. High surface area material such as 10 micron powder may autoignite at room temperature. Fine chips, turnings, or grinding dust produced from this metal are flammable. Ignition point for powder varies from 200 oC to above 500 oC depending on particle size.
Minimum Explosible Concentration (g/m3): Less than 100. Varies with particle size.
Extinguishing Media: Dry table salt. Type D fire extinguisher. DO NOT USE water, carbon dioxide or halocarbon extinguishing agent.
Special Firefighting Procedures: If metal fines become ignited it is advisable to allow the material to burnout. Fire can be controlled by smothering with dry table salt or using Type D dry-powder fire extinguisher material. Wear reflective heat-resistant suit.
Unusual Fire & Explosion Hazard: Do not spray water on burning zirconium. Carbon dioxide is not effective in extinguishing burning zirconium.
If a fire starts in a mass of wet metal fines, the initial fire may be followed by an explosion. Therefore, when in doubt, personnel should retire and not attempt to extinguish the fire. The explosive characteristic of such material is caused by the steam and hydrogen generated within the burning mass.
Spontaneously combustible in dry powder form. Flammable and explosive as dust or powder, also in the form of borings and shavings. Zirconium metal is a very dangerous fire hazard in the form of dust when exposed to heat, flame or by chemical reaction with oxidizing agents. May be an explosion hazard in the form of dust by chemical reaction with air, alkali hydroxides, alkali metal chromates, dichromates, molybdates, sulfates, tungstates, borax, CCl4, copper oxide, lead, lead oxide, phosphorous, KClO3, KNO3, nitryl fluoride. May be extremely sensitive to shock, and static electricity may cause spontaneous ignition.